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Noble Metal Alloys Properties

Noble Metal Alloys Model Library

A Property Model designed to assist users in achieving an attractive color when developing noble metal alloys for the purpose of cosmetic applications.

About the Noble Metal Alloys Model Library

Noble metal alloys are frequently developed for the purpose of achieving an attractive color. In particular, the Au-Ag-Pt-Cu-Al system is of interest. The Noble Metal Alloys Model Library includes one model that was designed for predicting the optical properties and apparent color of noble metal alloys as a function of incident light and other important variables. The model is intended to assist users in achieving an attractive color when developing noble metal alloys for the purpose of cosmetic applications. 

The Noble Metal Alloys Model Library is available for free to all users who have or upgrade to the Noble Metal Alloys Database (TCNOBL) (version 3 or newer) and who have a valid Maintenance and Support Subscription.

About the Optical Properties Model

The Optical Properties Model is used to simulate the color, reflection, and transmission of light, based on modeling the alloy microstructure and the resulting optical properties. The model is intended to assist users in achieving an attractive color when developing noble metal alloys for the purpose of cosmetic applications. The model calculates dielectric function and the refractive properties of the phases as a function of composition and then appropriately averages these over the entire microstructure.

Use Cases of the Optical Properties Model

The Optical Properties Model has many use cases, but three are discussed below:

Screening the Color of an Alloy System

The Optical Properties Model can be used to screen the color of an alloy system so that users can find the colors that are optimal for their application. The plot shown here is for an Au-Ag-Cu system. In the example, the entire composition space was screened with a 2 wt.% step size. The alloy microstructure was obtained at each step as annealed at 873.15 K to obtain the equilibrium phases and compositions for accurate color prediction. The standard illuminant is D65 noon daylight, with a 2˚ standard observer viewing angle. The material is assumed to be opaque with a thickness of 10,000 nm.

The Optical Properties Model, screening of the color of an Au-Ag-Cu system.

Designing a Green Gold Alloy by Adjusting Ag Content in Au-10Cu-xAg Alloys

The Optical Properties Model can also be used to design specific colors of gold alloys, such as green or purple gold. The plot here shows the change of color difference (ΔE) between the targeting light green gold color and the simulated alloy color when changing Ag. The target color in Lab color space is [95, -13, 25], representing a light green shade.

The Optical Properties Model. Thee plot here shows the change of color difference (ΔE) between the targeting light green gold color and the simulated alloy color when changing Ag.

Visualizing the Impact of Alloy Thickness and Light Incident Angle on Color

The Optical Properties Model can also be used to visualize the impact of alloy thickness and light incident angle on the color of an alloy, as shown in the plot here for an Ag-Au-Cu system. For this example, intercritical annealing was not selected, as all elements were assumed to dissolve in the FCC phase of pure gold. As can be seen in the plot, as the material thickness increases, the color of gold tends to approach the bulk gold color observed in macroscopic samples.

The Optical Properties Model can also be used to visualize the impact of alloy thickness and light incident angle on the color of an alloy, as shown in the plot here for an Ag-Au-Cu system.

The plots above are taken from the example: PM_Noble_01_Color_Prediction. This example demonstrates three use cases for simulating color in the Ag-Au-Cu alloy system: screening the color of the alloy system, designing a green-gold alloy by adjusting Ag content, and visualizing the impact of alloy thickness and light incident angle on color. The example is included in the Noble Metal Alloys Model Library and is available from within the software from the Help menu > Example Files > Property models > Noble Metal Alloys.

Request a Free Consultation

The Noble Metal Alloys Model Library is available for free to all users who have or upgrade to the Noble Metal Alloys Database (TCNOBL) (version 3 or newer) and who have a valid Maintenance and Support Subscription. 

If you’re new to Thermo-Calc or looking to expand your license, we invite you to schedule a free consultation with us. Together, we’ll discuss your needs and determine whether the Noble Metal Alloys Model Library is the right fit for you. If you already know that you’re interested, you’re also welcome to request a quotation.

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