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Metal Slag and Oxides Database

Thermo-Calc Software offers one database designed for metal slag and oxides, TCOX14 the Metal Oxide Solutions Database.

Technical Information Sheet for TCOX14

Validation and Calculation Examples for TCOX14

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TCOX14 Quick Overview

  • PROPERTIES:
    • Gibbs Energy
      • Volume
        • Viscosity of molten slags
          • Surface tension of molten slags
            • Electrical conductivity
              • Electrical resistivity
                • Thermal conductivity
                  • Thermal resistivity
                  • ELEMENTS: Al, Ar, B, Ba, C, Ca, Co, Cr, Cu, F, Fe, Gd, H, Hf, K, La, Li, Mg, Mn, Mo, N, Na, Nb, Ni, O, P, S, Si, Ti, V, W, Y, Yb, Zr
                  • ASSESSED PHASES: 744
Properties Calculated

Metal Oxide Solutions Database

TCOX14 is a thermodynamic and properties database used for application to slags and oxides. The intended application is for solid and liquid ionized materials, for example oxides or sulfides. Despite the name of the database, it can also be used for fluoride and sulfide systems without oxygen.

Common applications of the database include:

  • Development of ceramics
  • Slags
  • Refractories
  • Metallurgical processing (for example slag and liquid metal interactions)
  • ESR slags
  • Materials corrosion
  • Thermal Barrier Coatings (TBC)
  • Yttria-Stabilised-Zirconia (YSZ)
  • Solid oxide fuel cell materials
  • Sulfide formation
  • Dephosphorization and desulfurization
  • Recovery of lithium in the pyrometallurgical processing of lithium-ion battery recycling
  • And more

TCOX14 was developed to be used with nearly our entire suite of products: Thermo-Calc, the Add-on Modules, except for the Additive Manufacturing Module, and all available SDKs.

Featured Publication

The following publication explores how thermodynamic and properties databases, including TCOX, can be used to help design more durable coating materials for gas turbine engines.

David L. Poerschke
Developments in Thermodynamic Models of Deposit-Induced Corrosion of High-Temperature Coatings
JOM, Volume (2021)

Read the paper

Compatible with the Process Metallurgy Module

TCOX14 is compatible with the Process Metallurgy Module, an Add-on Module used for advanced calculations involving slag, metal, and gas. The Module is primarily designed for application to steelmaking and steel refining processes including converters, such as basic oxygen furnaces (BOF), electric arc furnaces (EAF), ladle furnace (LF) metallurgy, and more. The Module can also be applied to other metallurgical processes.

Learn about the Process Metallurgy Module

Applications

Read about the primary applications for the TCOX database.

Background for Process Metallurgy.

Process Metallurgy

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Background for Refractory Oxides.

Refractory Oxides

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Background for Slags.

Slags

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USE CASE

First of Its Kind Physical Model of Secondary Steelmaking Metallurgy 

Read about the development of a fully automated physical model of secondary steelmaking metallurgy by Thermo-Calc Software and the German steel producer Georgsmarienhütte GmbH (GMH). The first of its kind known in the industry, the model uses the Metal Oxide Solutions Database and the Process Metallurgy Module to provide detailed information about each process step, helping GMH gain deep insights into their metallurgical processes and significantly improves process understanding.

Read about the Project
thermo-calc-software-solutions>

Solutions

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Showcase

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